Science
How a Record-Breaking Copper Catalyst Converts CO2 Into Liquid Fuels
Researchers at Berkeley Lab have made real-time movies of copper nanoparticles as they evolve to convert carbon dioxide and water into renewable fuels and chemicals. Their new insights could help advance the next generation of solar fuels
Video of a 4D-STEM experiment: Berkeley Lab researchers used a new electrochemical liquid cell to observe copper nanoparticles (ranging in size from 7 nanometers to 18 nanometers) evolve into active nanograins during CO2 electrolysis – a process that uses electricity to drive a reaction on the surface of an electrocatalyst. The new electrochemical liquid cell allows researchers to resolve images of objects smaller than 10 nanometers.
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Newswise — Since the 1970s, scientists have known that copper has a special ability to transform carbon dioxide into valuable chemicals and fuels. But for many years, scientists have struggled to understand how this common metal works as an electrocatalyst, a mechanism that uses energy from electrons to chemically transform molecules into different products.
Now, a research team led by Lawrence Berkeley National Laboratory (Berkeley Lab) has gained new insight by capturing real-time movies of copper nanoparticles (copper particles engineered at the scale of a billionth of a meter) as they convert CO2 and water into renewable fuels and chemicals: ethylene, ethanol, and propanol, among others. The work was reported in the journal Nature last week.
“This is very exciting. After decades of work, we’re finally able to show – with undeniable proof – how copper electrocatalysts excel in CO2 reduction,” said Peidong Yang, a senior faculty scientist in Berkeley Lab’s Materials Sciences and Chemical Sciences Divisions who led the study. Yang is also a professor of chemistry and materials science and engineering at UC Berkeley. “Knowing how copper is such an excellent electrocatalyst brings us steps closer to turning CO2 into new, renewable solar fuels through artificial photosynthesis.”
The work was made possible by combining a new imaging technique called operando 4D electrochemical liquid-cell STEM (scanning transmission electron microscopy) with a soft X-ray probe to investigate the same sample environment: copper nanoparticles in liquid. First author Yao Yang, a UC Berkeley Miller postdoctoral fellow, conceived the groundbreaking approach under the guidance of Peidong Yang while working toward his Ph.D. in chemistry at Cornell University.
Credit: Thor Swift/Berkeley Lab
(From left to right): Julian Feijoo, Jianbo Jin, Cheng Wang, Peidong Yang, Yao Yang, Inwhan Roh, and Maria Fonseca Guzman at the Advanced Light Source.
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Artist’s rendering of a copper nanoparticle as it evolves during CO2 electrolysis: Copper nanoparticles (left) combine into larger metallic copper “nanograins” (right) within seconds of the electrochemical reaction, reducing CO2 into new multicarbon products.
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Credit: Thor Swift/Berkeley Lab
Yao Yang (center) loads a sample into the soft X-ray scattering chamber as Cheng Wang (left) and Peidong Yang (right) observe at the RSoXS Beamline (Beamline 11.0.1.2) at the Advanced Light Source.
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Scientists who study artificial photosynthesis materials and reactions have wanted to combine the power of an electron probe with X-rays, but the two techniques typically can’t be performed by the same instrument.
Electron microscopes (such as STEM or TEM) use beams of electrons and excel at characterizing the atomic structure in parts of a material. In recent years, 4D STEM (or “2D raster of 2D diffraction patterns using scanning transmission electron microscopy”) instruments, such as those at Berkeley Lab’s Molecular Foundry, have pushed the boundaries of electron microscopy even further, enabling scientists to map out atomic or molecular regions in a variety of materials, from hard metallic glass to soft, flexible films.
On the other hand, soft (or lower-energy) X-rays are useful for identifying and tracking chemical reactions in real time in an operando, or real-world, environment.
But now, scientists can have the best of both worlds. At the heart of the new technique is an electrochemical “liquid cell” sample holder with remarkable versatility. A thousand times thinner than a human hair, the device is compatible with both STEM and X-ray instruments.
The electrochemical liquid cell’s ultrathin design allows reliable imaging of delicate samples while protecting them from electron beam damage. A special electrode custom-designed by co-author Cheng Wang, a staff scientist at Berkeley Lab’s Advanced Light Source, enabled the team to conduct X-ray experiments with the electrochemical liquid cell. Combining the two allows researchers to comprehensively characterize electrochemical reactions in real time and at the nanoscale.
Getting granular
During 4D-STEM experiments, Yao Yang and team used the new electrochemical liquid cell to observe copper nanoparticles (ranging in size from 7 nanometers to 18 nanometers) evolve into active nanograins during CO2 electrolysis – a process that uses electricity to drive a reaction on the surface of an electrocatalyst.
The experiments revealed a surprise: copper nanoparticles combined into larger metallic copper “nanograins” within seconds of the electrochemical reaction.
To learn more, the team turned to Wang, who pioneered a technique known as “resonant soft X-ray scattering (RSoXS) for soft materials,” at the Advanced Light Source more than 10 years ago.
With help from Wang, the research team used the same electrochemical liquid cell, but this time during RSoXS experiments, to determine whether copper nanograins facilitate CO2 reduction. Soft X-rays are ideal for studying how copper electrocatalysts evolve during CO2 reduction, Wang explained. By using RSoXS, researchers can monitor multiple reactions between thousands of nanoparticles in real time, and accurately identify chemical reactants and products.
The RSoXS experiments at the Advanced Light Source – along with additional evidence gathered at Cornell High Energy Synchrotron Source (CHESS) – proved that metallic copper nanograins serve as active sites for CO2 reduction. (Metallic copper, also known as copper(0), is a form of the element copper.)
During CO2 electrolysis, the copper nanoparticles change their structure during a process called “electrochemical scrambling.” The copper nanoparticles’ surface layer of oxide degrades, creating open sites on the copper surface for CO2 molecules to attach, explained Peidong Yang. And as CO2 “docks” or binds to the copper nanograin surface, electrons are then transferred to CO2, causing a reaction that simultaneously produces ethylene, ethanol, and propanol along with other multicarbon products.
“The copper nanograins essentially turn into little chemical manufacturing factories,” Yao Yang said.
Further experiments at the Molecular Foundry, the Advanced Light Source, and CHESS revealed that size matters. All of the 7-nanometer copper nanoparticles participated in CO2 reduction, whereas the larger nanoparticles did not. In addition, the team learned that only metallic copper can efficiently reduce CO2 into multicarbon products. The findings have implications for “rationally designing efficient CO2 electrocatalysts,” Peidong Yang said.
The new study also validated Peidong Yang’s findings from 2017: That the 7-nanometer-sized copper nanoparticles require low inputs of energy to start CO2 reduction. As an electrocatalyst, the 7-nanometer copper nanoparticles required a record-low driving force that is about 300 millivolts less than typical bulk copper electrocatalysts. The best-performing catalysts that produce multicarbon products from CO2 typically operate at high driving force of 1 volt.
The copper nanograins could potentially boost the energy efficiency and productivity of some catalysts designed for artificial photosynthesis, a field of research that aims to produce solar fuels from sunlight, water, and CO2. Currently, researchers within the Department of Energy-funded Liquid Sunlight Alliance (LiSA) plan to use the copper nanograin catalysts in the design of future solar fuel devices.
“The technique’s ability to record real-time movies of a chemical process opens up exciting opportunities to study many other electrochemical energy conversion processes. It’s a huge breakthrough, and it would not have been possible without Yao and his pioneering work,” Peidong Yang said.
Researchers from Berkeley Lab, UC Berkeley, and Cornell University contributed to the work. Other authors on the paper include co-first authors Sheena Louisa and Sunmoon Yu, former UC Berkeley Ph.D. students in Peidong Yang’s group, along with Jianbo Jin, Inwhan Roh, Chubai Chen, Maria V. Fonseca Guzman, Julian Feijóo, Peng-Cheng Chen, Hongsen Wang, Christopher Pollock, Xin Huang, Yu-Tsuan Shao, Cheng Wang, David A. Muller, and Héctor D. Abruña.
Parts of the experiments were performed by Yao Yang at Cornell under the supervision of Héctor Abruña, professor of chemistry and chemical biology, and David A. Muller, professor of engineering.
This work was supported by the DOE Office of Science.
The Molecular Foundry and Advanced Light Source are user facilities at Berkeley Lab.
Source: Lawrence Berkeley National Laboratory
Science
October Meteor Showers Give Phoenix Skywatchers a Reason to Look Up
Phoenix skywatchers have several chances to catch October’s meteor showers. Here’s when to watch the Taurids and Orionids—and how moonlight affects the view.
Last Updated on October 10, 2026 by Daily News Staff
PHOENIX — October is bringing several opportunities to spot shooting stars over the Valley, with the Draconids reaching their October 8–9 peak and more meteor activity ahead.
The Draconids remain active through October 10, although viewers should expect a light display as the peak passes. Under favorable conditions, the shower typically produces only a handful of meteors per hour. timeanddate.com
Next, the Southern Taurids have an annual activity peak around October 14. Known for occasional bright fireballs, the shower continues into November. The stronger Orionids peak on the night of October 21 into the morning of October 22, typically producing 10–20 meteors per hour under dark skies. A bright Moon will interfere with this year’s display. American Meteor Society
The Orionids originate from debris left by Halley’s Comet. For Phoenix viewers, the best opportunity will be after moonset and before dawn, weather permitting. City lights will further reduce the number visible. amsmeteors.org
NASA recommends finding a viewing area away from streetlights, allowing about 30 minutes for eyes to adjust, and watching a broad stretch of sky. No telescope is needed—just a comfortable chair and patience. NASA Science
ECurious about what’s happening above us? Explore more space stories and science explainers in The Knowledge at STM Daily News.xplore more space, science and everyday
unknown
Did Jackie Gleason See Aliens? Inside the Strange Nixon–UFO Legend
Jackie Gleason reportedly told his wife that President Richard Nixon arranged for him to view preserved extraterrestrial bodies at a Florida Air Force base. Here is what we know—and why the remarkable story remains unverified.
The beloved comedian reportedly told his wife that President Richard Nixon arranged for him to view preserved extraterrestrial bodies at a Florida Air Force base. Decades later, the extraordinary story remains fascinating—but unverified.
Jackie Gleason is remembered as “The Great One,” the larger-than-life entertainer who turned bus driver Ralph Kramden into one of television’s most enduring characters on The Honeymooners. Away from the cameras, however, Gleason had another consuming interest: UFOs, psychic phenomena and the possibility of extraterrestrial life.
That interest eventually became the foundation of one of the strangest stories ever associated with an American president and a Hollywood celebrity. According to Gleason’s second wife, Beverly McKittrick, her husband came home late one night in 1973 and claimed that President Richard Nixon had helped him see the preserved bodies of extraterrestrial beings at Homestead Air Force Base in Florida.
Did Jackie Gleason really see aliens?
The honest answer is that we do not know. The allegation is remarkable, but the available evidence never rises above an uncorroborated story attributed to Gleason years after the supposed event.
Gleason’s fascination with UFOs was real
There is little question that Gleason took the UFO subject seriously. He reportedly assembled a substantial personal library devoted to UFOs, the paranormal and related mysteries. His unusual circular home in New York—often nicknamed “The Mothership”—only strengthened his public association with flying saucers, although its distinctive architecture is not evidence of an extraterrestrial encounter.
Gleason also had a genuine social connection with Nixon. The two men shared an interest in golf and spent time together in Florida. That documented friendship is the factual starting point from which the more sensational story grew.
The alleged trip to Homestead Air Force Base
McKittrick said that Gleason returned to their Florida home at about 11:30 one evening looking disturbed. According to her account, he told her that Nixon had arrived without the usual presidential entourage and taken him to Homestead Air Force Base, south of Miami.
Once there, Gleason allegedly entered a secured building where he saw small humanoid bodies preserved inside glass-topped containers. Published versions differ over the number of bodies and some physical details, but they generally describe child-sized beings with oversized heads.
Importantly, McKittrick did not claim to have accompanied the men or witnessed anything at the base. Her account was based entirely on what she said Gleason told her after returning home.
The story became public in 1983, years after the alleged visit and after the couple had divorced. It circulated widely through tabloid reporting, UFO publications and later books, gradually becoming part of UFO folklore.
Why the story remains unverified
No authenticated photograph, visitor record, military document or firsthand statement from Nixon has emerged to confirm the alleged trip. Gleason also never provided investigators with a signed affidavit describing the experience.
UFO researcher Larry Bryant reportedly sought records from Homestead and tried to obtain a statement from Gleason, but those efforts produced no confirming documentation. Gleason’s refusal to address the account publicly has sometimes been portrayed as suspicious, but silence is not proof that an event occurred.
There is another important complication: McKittrick later expressed uncertainty about her former husband’s story.
During telephone interviews conducted by researcher Kenny Young in 2003, she stood by her recollection that Gleason told her he had seen “dead aliens.” She also acknowledged that, as the years passed, she wondered whether he might have invented the explanation because he had been out late. She declined to appear on camera and said the story should be authenticated first.
Her later comments do not establish that the account was false, but they considerably weaken any attempt to treat it as verified history.
Could a president have slipped away unnoticed?
Some versions of the legend emphasize that Nixon supposedly drove to Gleason’s house alone and then entered a military installation without his Secret Service detail. Presidents have occasionally sought privacy or slipped away from tightly managed schedules, but a secret nighttime excursion of this nature would have involved serious security and logistical obstacles.
The claim becomes even more difficult to accept when we consider what Nixon allegedly revealed. If the United States possessed extraterrestrial bodies, granting a comedian personal access to them would have represented an extraordinary breach of national security—with no apparent official purpose and no surviving documentation.
None of that makes the episode logically impossible. It does, however, mean that the story requires exceptionally strong evidence. That evidence has never appeared.
A compelling legend, not a confirmed encounter
The Jackie Gleason story endures because it combines three irresistible ingredients: a famous comedian fascinated by UFOs, a secretive American president and a nighttime visit to a military base containing an alleged government secret.
What can be established is that Gleason was deeply interested in UFOs, knew Nixon and was said by his former wife to have made an extraordinary claim. What cannot be established is that Nixon took him to Homestead Air Force Base or that preserved extraterrestrial bodies were ever stored there.
So, did Jackie Gleason see aliens?
Perhaps he believed that he did—or perhaps he simply told an unforgettable story. Until corroborating evidence emerges, the alleged encounter belongs in the intriguing borderland between celebrity history and American UFO mythology.
Sources and further reading
- The Black Vault: Jackie Gleason and the Pickled Alien
- University of Miami Libraries: The Jackie Gleason Collection
- U.S. Department of Defense: All-domain Anomaly Resolution Office
Step into The Unknown, where STM Daily News explores the strange phenomena, unexplained encounters and enduring mysteries that continue to challenge what we think we know. From UFO sightings and paranormal events to historical mysteries and unusual scientific discoveries, we examine the stories, evidence and competing explanations—without losing our sense of wonder. https://stmdailynews.com/science/unknown/
health and wellness
Lactose intolerance is actually the human norm – but racism, the US government and business interests have made it into a condition
Lactose intolerance is the global human norm, but Western dietary standards, government policies and commercial interests helped frame it as a medical deficiency.
Hilary Smith, University of Denver
Lactose intolerance makes drinking milk or eating ice cream a literal pain. For some people, eating a dairy treat can lead to bloating, nausea and diarrhea. You might’ve experienced its effects yourself. If so, you may think of lactose intolerance as a defect rather than the norm.
But did you know that most people in the world today are lactose intolerant – and that the condition itself was invented in the 1960s?
“Surely you mean discovered, not invented,” I hear you saying. I don’t. As a historian who has traced the origins of nutrition-science ideas, I have chosen the word “invented” on purpose.
Inventing lactose intolerance
Variations in people’s ability to digest lactose first came to scientists’ attention after American dairy producers found a way to rid themselves of a postwar milk surplus. To offload what they couldn’t sell, they looked to the government to intervene. And it did, buying the excess and embedding it in school lunches and other places with publicly funded meals.
Suddenly, many people who had not habitually drunk milk were consuming it regularly, including not only some Americans but also people overseas. Part of that same milk surplus found its way into school lunches in places such as Japan and Taiwan in the 1950s as the American government began to sell milk to allies during the Cold War.
Many of the groups drinking milk regularly for the first time did not like it. In fact, it made them feel sick. Intrigued, scientists set up experiments to figure out why. In a 1966 study comparing how Black and white people incarcerated in Baltimore metabolized lactose, researchers found that Black participants had lower levels of lactase – the enzyme that breaks down lactose – in their guts.
To the white scientists conducting this study, the trouble that the Black prisoners had digesting milk looked like an “inborn error of metabolism.” They assumed that the normal human state was lactose tolerance and that the lactose intolerant had inherited a genetic mutation.
It was only after years more work with research participants of many races that experts realized that, as one National Institutes of Health official put it in 1981, “lactose intolerance is a normal physiological condition, shared by every adult animal except for certain ethnic and racial groups in man.” People of northern European descent, it turned out, were the weird ones. It was their ancestors who had passed down a genetic mutation – one that made them able to digest milk after infancy.
In short, what scientists discovered in the 1960s was that different bodies process milk differently. What they invented was the idea that lactose intolerance is a defect. Accepting that framing would mean nearly two-thirds of the human population – the estimated prevalence of lactose intolerance worldwide – is defective.
Instead of acknowledging that dairy-free diets can be healthy, people innovated ways to overcome this supposed disability so everyone could consume more.
Nutritional imperialism
Lactose intolerance is one example of what I call nutritional imperialism: a way of thinking that treats white diets as the norm and everyone else’s as an aberration.
Nutritional imperialism was common in the 20th century, when scientists thought that not only milk-rich but also meat-heavy diets were best; they considered diets outside of the United States and Europe too vegetarian. Some also argued that wheat flour, not rice, ought to be the universal staple.
The same bias applied to bodies. Besides faulty lactose digestion, nonwhite bodies were accused of other failures, too, such as aldehyde dehydrogenase deficiency, an inability to digest alcohol quickly. The less technical term for this may be more familiar: Asian flush.
Such differences might have been thought of as variety, just another way of being human. Instead, each became a deficiency.
Many people today have inherited and perpetuated this way of thinking without knowing it, including those who are deemed deficient by it. In 1959, the director of Japan’s nutrition bureau declared that “rice-eating peoples” such as the Japanese were “resigned and passive” and could correct this by imitating Western diets and switching to wheat.
Today, the most prominent scientist promoting the idea that Asian flush is a disease is a geneticist of Taiwanese descent who started a research consortium to study “the most common human enzymopathy in the world.”
The Chinese Nutrition Society placed a tall glass of milk next to its 2022 Food Guide Plate – never mind estimates that the vast majority of Han Chinese, the largest ethnic group in China and worldwide, are lactose intolerant.
Turning sickness back into difference
Science that pathologizes difference helps racism persist.
In recent years, white supremacists have embraced the concept of lactose intolerance as a distinguishing debility of nonwhite people. Social media users have copied and pasted a map of the geographic distribution of lactose tolerance originally published in the scientific journal Nature into racist chat threads on the online discussion forum 4chan.
In 2017, internet trolls disrupted an anti-racist art installation with neo-Nazi chants and messily downed jugs of milk to accentuate their white identity.
Turning a lactose-digestion difference into a deficiency has done more to reinforce narratives of racial hierarchy than to improve public health. So here’s a suggestion: If you enjoy eating dairy, keep doing it; if you don’t, don’t – and know that there is nothing wrong with you.
Hilary Smith, Professor of History, University of Denver
This article is republished from The Conversation under a Creative Commons license. Read the original article.
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