Science

How a Record-Breaking Copper Catalyst Converts CO2 Into Liquid Fuels

Published

2 years ago

February 28, 2023

Daily News Staff

Researchers at Berkeley Lab have made real-time movies of copper nanoparticles as they evolve to convert carbon dioxide and water into renewable fuels and chemicals. Their new insights could help advance the next generation of solar fuels

Credit: Yao Yang/Berkeley Lab. Courtesy of Nature.
Video of a 4D-STEM experiment: Berkeley Lab researchers used a new electrochemical liquid cell to observe copper nanoparticles (ranging in size from 7 nanometers to 18 nanometers) evolve into active nanograins during CO2 electrolysis – a process that uses electricity to drive a reaction on the surface of an electrocatalyst. The new electrochemical liquid cell allows researchers to resolve images of objects smaller than 10 nanometers.
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Newswise — Since the 1970s, scientists have known that copper has a special ability to transform carbon dioxide into valuable chemicals and fuels. But for many years, scientists have struggled to understand how this common metal works as an electrocatalyst, a mechanism that uses energy from electrons to chemically transform molecules into different products.

Now, a research team led by Lawrence Berkeley National Laboratory (Berkeley Lab) has gained new insight by capturing real-time movies of copper nanoparticles (copper particles engineered at the scale of a billionth of a meter) as they convert CO₂ and water into renewable fuels and chemicals: ethylene, ethanol, and propanol, among others. The work was reported in the journal Nature last week.

“This is very exciting. After decades of work, we’re finally able to show – with undeniable proof – how copper electrocatalysts excel in CO₂ reduction,” said Peidong Yang, a senior faculty scientist in Berkeley Lab’s Materials Sciences and Chemical Sciences Divisions who led the study. Yang is also a professor of chemistry and materials science and engineering at UC Berkeley. “Knowing how copper is such an excellent electrocatalyst brings us steps closer to turning CO₂ into new, renewable solar fuels through artificial photosynthesis.”

The work was made possible by combining a new imaging technique called operando 4D electrochemical liquid-cell STEM (scanning transmission electron microscopy) with a soft X-ray probe to investigate the same sample environment: copper nanoparticles in liquid. First author Yao Yang, a UC Berkeley Miller postdoctoral fellow, conceived the groundbreaking approach under the guidance of Peidong Yang while working toward his Ph.D. in chemistry at Cornell University.

Credit: Thor Swift/Berkeley Lab
(From left to right): Julian Feijoo, Jianbo Jin, Cheng Wang, Peidong Yang, Yao Yang, Inwhan Roh, and Maria Fonseca Guzman at the Advanced Light Source.
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Scientists who study artificial photosynthesis materials and reactions have wanted to combine the power of an electron probe with X-rays, but the two techniques typically can’t be performed by the same instrument.

Electron microscopes (such as STEM or TEM) use beams of electrons and excel at characterizing the atomic structure in parts of a material. In recent years, 4D STEM (or “2D raster of 2D diffraction patterns using scanning transmission electron microscopy”) instruments, such as those at Berkeley Lab’s Molecular Foundry, have pushed the boundaries of electron microscopy even further, enabling scientists to map out atomic or molecular regions in a variety of materials, from hard metallic glass to soft, flexible films.

On the other hand, soft (or lower-energy) X-rays are useful for identifying and tracking chemical reactions in real time in an operando, or real-world, environment.

But now, scientists can have the best of both worlds. At the heart of the new technique is an electrochemical “liquid cell” sample holder with remarkable versatility. A thousand times thinner than a human hair, the device is compatible with both STEM and X-ray instruments.

The electrochemical liquid cell’s ultrathin design allows reliable imaging of delicate samples while protecting them from electron beam damage. A special electrode custom-designed by co-author Cheng Wang, a staff scientist at Berkeley Lab’s Advanced Light Source, enabled the team to conduct X-ray experiments with the electrochemical liquid cell. Combining the two allows researchers to comprehensively characterize electrochemical reactions in real time and at the nanoscale.

Getting granular

During 4D-STEM experiments, Yao Yang and team used the new electrochemical liquid cell to observe copper nanoparticles (ranging in size from 7 nanometers to 18 nanometers) evolve into active nanograins during CO₂ electrolysis – a process that uses electricity to drive a reaction on the surface of an electrocatalyst.

The experiments revealed a surprise: copper nanoparticles combined into larger metallic copper “nanograins” within seconds of the electrochemical reaction.

To learn more, the team turned to Wang, who pioneered a technique known as “resonant soft X-ray scattering (RSoXS) for soft materials,” at the Advanced Light Source more than 10 years ago.

With help from Wang, the research team used the same electrochemical liquid cell, but this time during RSoXS experiments, to determine whether copper nanograins facilitate CO₂reduction. Soft X-rays are ideal for studying how copper electrocatalysts evolve during CO₂ reduction, Wang explained. By using RSoXS, researchers can monitor multiple reactions between thousands of nanoparticles in real time, and accurately identify chemical reactants and products.

The RSoXS experiments at the Advanced Light Source – along with additional evidence gathered at Cornell High Energy Synchrotron Source (CHESS) – proved that metallic copper nanograins serve as active sites for CO₂ reduction. (Metallic copper, also known as copper(0), is a form of the element copper.)

During CO₂ electrolysis, the copper nanoparticles change their structure during a process called “electrochemical scrambling.” The copper nanoparticles’ surface layer of oxide degrades, creating open sites on the copper surface for CO₂ molecules to attach, explained Peidong Yang. And as CO₂ “docks” or binds to the copper nanograin surface, electrons are then transferred to CO₂, causing a reaction that simultaneously produces ethylene, ethanol, and propanol along with other multicarbon products.

“The copper nanograins essentially turn into little chemical manufacturing factories,” Yao Yang said.

Further experiments at the Molecular Foundry, the Advanced Light Source, and CHESS revealed that size matters. All of the 7-nanometer copper nanoparticles participated in CO₂ reduction, whereas the larger nanoparticles did not. In addition, the team learned that only metallic copper can efficiently reduce CO₂into multicarbon products. The findings have implications for “rationally designing efficient CO₂ electrocatalysts,” Peidong Yang said.

The new study also validated Peidong Yang’s findings from 2017: That the 7-nanometer-sized copper nanoparticles require low inputs of energy to start CO₂ reduction. As an electrocatalyst, the 7-nanometer copper nanoparticles required a record-low driving force that is about 300 millivolts less than typical bulk copper electrocatalysts. The best-performing catalysts that produce multicarbon products from CO₂ typically operate at high driving force of 1 volt.

The copper nanograins could potentially boost the energy efficiency and productivity of some catalysts designed for artificial photosynthesis, a field of research that aims to produce solar fuels from sunlight, water, and CO₂. Currently, researchers within the Department of Energy-funded Liquid Sunlight Alliance (LiSA) plan to use the copper nanograin catalysts in the design of future solar fuel devices.

“The technique’s ability to record real-time movies of a chemical process opens up exciting opportunities to study many other electrochemical energy conversion processes. It’s a huge breakthrough, and it would not have been possible without Yao and his pioneering work,” Peidong Yang said.

Researchers from Berkeley Lab, UC Berkeley, and Cornell University contributed to the work. Other authors on the paper include co-first authors Sheena Louisa and Sunmoon Yu, former UC Berkeley Ph.D. students in Peidong Yang’s group, along with Jianbo Jin, Inwhan Roh, Chubai Chen, Maria V. Fonseca Guzman, Julian Feijóo, Peng-Cheng Chen, Hongsen Wang, Christopher Pollock, Xin Huang, Yu-Tsuan Shao, Cheng Wang, David A. Muller, and Héctor D. Abruña.

Parts of the experiments were performed by Yao Yang at Cornell under the supervision of Héctor Abruña, professor of chemistry and chemical biology, and David A. Muller, professor of engineering.

This work was supported by the DOE Office of Science.

The Molecular Foundry and Advanced Light Source are user facilities at Berkeley Lab.

Source: Lawrence Berkeley National Laboratory

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Stargazing Delight: Catch the Ursid Meteor Shower This Sunday Morning!

Published

6 hours ago

December 22, 2024

Lynette Young

As we cozy up to the end of another year, a delightful celestial event is gearing up to grace our skies: the Ursid meteor shower! Set to peak in the early morning hours of Sunday, December 22, this final meteor shower of the year offers a charming opportunity for some stargazing, even amidst the hustle and bustle of the holiday season.

A Little Background on the Ursids

Often overshadowed by the more prolific Geminid meteor shower that dazzles us just a week earlier, the Ursids tend to be a quieter affair. This year, their peak aligns perfectly with the winter solstice—the shortest day and longest night of the year. With the celestial display taking place during this time, there’s a unique chance to soak in some twinkling “shooting stars” above a snowy landscape.

@stmblog
🌌 Don’t miss the Ursid meteor shower this winter solstice! ✨ Bundle up, head outside, and enjoy the shooting stars! #Stargazing #Ursids ♬ original sound – STMDailyNews

Why Aren’t More People Watching?

Despite their charm, the Ursids are the least observed meteor shower, largely because of the busy holiday season and often unfavorable weather in the Northern Hemisphere—think cold nights filled with clouds. But if you missed the Geminids, fear not! The Ursids provide a wonderful pre-Christmas stargazing treat that is worth a look.

What to Expect from the Ursids

While the Ursids are not renowned for their activity—often delivering a mere 5 to 10 meteors per hour on a good night—there’s still magic in the unpredictability of astronomy. In years past, this meteor shower has surprised us with spectacular displays. Back in 1945 and 1968, observers saw around 100 meteors per hour, while the 1973 shower brought forth about 30 meteors! You never know when the Ursids may decide to put on a show, so keeping your eyes trained on the heavens could lead to some delightful surprises.

Understanding the Ursid Origin

The Ursids get their name from their radiant point in the sky, located in the constellation Ursa Minor, affectionately known as the Little Dipper. What we see as shooting stars are actually small fragments from the comet 8P/Tuttle, which Earth passes through each year. As the debris from the comet enters our atmosphere, it burns up and creates stunning streaks of light against the nighttime backdrop.

Tips for Optimal Viewing

So, how can you maximize your chances of catching the Ursid meteor shower this Sunday?

When to Watch: The Ursids run from December 17 to December 26, with the best viewing time occurring in the predawn hours of December 22. This is when the radiant is highest in the sky, offering the best chance to see those elusive meteors.
Find a Dark Spot: Get as far away from city lights as possible. A clear, dark sky will make it much easier to see the meteors.
Be Patient: Give your eyes time to adjust to the darkness—about 20 minutes is ideal. Bring a comfortable blanket or chair to sit back and enjoy the show.
Check the Weather: Clear skies are essential! Keep an eye on your local weather conditions to ensure a pleasant viewing experience.
Bring a Friend: Stargazing is always more fun when shared! Grab a friend or family member to join you, bringing some hot cocoa for added warmth and comfort.

As you bundle up and head outside this Sunday morning, remember to take a moment to appreciate the vastness of the universe above us. The Ursids may be a modest display compared to their more boisterous meteor shower counterparts, but each little shooting star tells a story of cosmic wonder and beauty. Happy stargazing, and may your sky be filled with twinkling lights! ✨

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Mysterious Lights Over Oregon: Pilots Report Unusual Aerial Phenomena

Published

3 days ago

December 19, 2024

Rod Washington

This past weekend, the skies of Oregon became the backdrop for an extraordinary event that has both puzzled and dazzled observers. At least four commercial pilots reported encountering unexplained bright lights displaying incredible speeds and erratic movements, renewing interest and debate about aerial phenomena.

The Encounter Details

The first report came from a pilot operating an air ambulance who described a startling experience. A bright, red light zoomed towards his Life Flight plane, only to reverse direction and head back towards the Pacific Ocean at bewildering speeds. The event left the pilot and his crew astounded by the light’s velocity and abrupt maneuvers.

Meanwhile, the pilot of a United Airlines flight over Eugene also reported seeing multiple mysterious objects. These unidentified lights moved vertically and horizontally in patterns that defied easy explanation, with no evidence of military activity in the area at the time.

Adding to the intrigue, the Life Flight pilot noted that one of the lights engaged in a corkscrew pattern, an observation that was corroborated by the aircraft’s collision avoidance system. Air traffic control, maintaining a cautious approach, authorized the pilot to maneuver as necessary to maintain safety.

@stmblog
Spotted strange lights in Oregon’s skies? You’re not alone! UFO sightings are on the rise. #OregonUFOSightings #MysteriousLights 🛸✨ ♬ original sound – STMDailyNews

https://www.tiktok.com/t/ZTYVWd4ew

Visual Evidence and Continued Sightings

Throughout these encounters, several pilots managed to capture brief video clips. These clips, although hard to discern due to the dark conditions, show glimpses of the unusual red, circular lights. Another report from two Horizon Airlines pilots further confirmed that whatever was out there wasn’t isolated to a single incident or observer.

Experts Weigh In: Possible Explanations

In the wake of these mystifying sightings, experts have been quick to offer explanations. Douglas Buettner, a scientist who has researched similar incidents, suggests that these lights could likely be flares from Starlink satellites. Starlink, a constellation designed by SpaceX to provide global broadband coverage, has been known to produce vivid optical flares when its panels reflect sunlight.

Buettner’s research, which includes previous pilot reports and observations, supports the idea that this natural reflection of sunlight could explain the phenomena observed. However, he also admits the current data is insufficient to conclusively rule out other possibilities.

Government and Public Response

Following these reports, the Federal Aviation Administration (FAA) confirmed the sighting of unidentified lights by a pilot, although they have not commented further. In a recent Senate hearing, the Pentagon’s director overseeing unidentified anomalous phenomena indicated a spike in such reports since the launch of satellite constellations like Starlink, underscoring the growing interest and concern regarding these observations.

The Broader Implications

While the most likely explanation for these mysterious lights points to satellite flares, the repeated occurrences of such phenomena continue to stir the public’s imagination and scientific curiosity. As we advance in our technological capabilities, the skies above us grow increasingly populated with human-made objects that can sometimes return to us as bewildering spectacles.

In either case, these events serve as a reminder of the vast and unexplored frontiers above us and the ever-present human quest for understanding the mysteries of our universe. Whether they turn out to be mundane or truly otherworldly, the skies over Oregon this weekend have given us all something to ponder and marvel at.

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New Jersey Drone Sightings: Unraveling the Mystery

Published

4 days ago

December 18, 2024

Rod Washington

In recent weeks, New Jersey has increasingly found itself under the watchful eye of mysterious drones. These sightings have captivated residents and officials alike, leading to widespread speculation and calls for action. Below is a comprehensive update on the current situation regarding drone sightings in the Garden State, including insights from government officials and community reactions.

The Surge of Sightings

Reports of large drones—up to six feet in diameter—flying over various regions of New Jersey have surged since mid-November. Assemblywoman Dawn Fantasia highlighted the unusual characteristics of these drones, often flying with their lights off and evading detection by traditional methods. Though the origin and purpose of these drones remain unclear, many are convinced that they are not the product of hobbyists.

Notably, many sightings have been concentrated near sensitive locations such as the Picatinny Arsenal, a U.S. military research facility, and Trump National Golf Club in Bedminster. Concerns have only intensified since these drones seem to be operating outside the realm of normal commercial or recreational use.

Government Investigations and Assurances

Federal and state law enforcement agencies, including the FBI and the Department of Homeland Security (DHS), have become actively involved in investigating these sightings. Despite receiving over 5,000 tips, officials state that there is currently no evidence suggesting that these drones pose a threat to national security or public safety. Instead, authorities believe that many of the reported sightings can be attributed to legal drones and other aerial phenomena, including misidentified manned aircraft and even celestial bodies like stars.

Governor Phil Murphy has reinforced this perspective, emphasizing that while drone sightings have raised valid concerns, there’s no immediate threat to public safety. The governor has called for federal assistance in the investigation and urged Congress to empower states with more authority to manage drone activities.

Congressional Response and Public Sentiment

The situation has sparked a debate among lawmakers, with some calling for stricter regulations or even a temporary ban on drone flights in New Jersey. Notably, two congressional representatives have gone so far as to request that the military intervene, highlighting the urgency felt by some constituents. U.S. Rep. Jeff Van Drew even suggested that a foreign entity could be behind the sightings, a theory that has been categorically denied by federal officials.

Public sentiment varies significantly, with many residents expressing concerns about the unknown nature of these drones. James Edwards from Succasunna has pointed out the anxiety gripping the community, noting, “There’s so much that’s unknown,” and calling for a measured response to the sightings.

The View from Washington

At the national level, President Joe Biden has responded to the growing unease, asserting that there is nothing nefarious behind the drone sightings. He emphasized the lawful presence of over one million registered drones operating across the country and assured the public that the situation is being closely monitored.

John Kirby, the White House National Security Advisor, reiterated that the majority of drone sightings do not indicate a coordinated threat and stem from common commercial, hobbyist, or law enforcement operations.

What Lies Ahead?

As investigations continue, officials stress the importance of discerning legitimate threats from unwarranted fears. The situation remains fluid, with ongoing dialogues both in Trenton and Washington to address public concerns and craft appropriate regulatory responses.

While the mystery of the New Jersey drones deepens, it’s vital for residents to remain calm and informed. As the investigation unravels the truths behind these sightings, a collective effort from the community, lawmakers, and federal agencies can help ensure safety and transparency in the skies above New Jersey.

Stay tuned for updates as this story continues to evolve, and be sure to report any new sightings or information to the appropriate authorities. Together, we can navigate the complexities of drone activity in our airspace while embracing this new technological frontier.